A national figure is a well-known person to Syrian society for their history, experiences, personal struggle, or for their ideas. The Coalition has 18 national figures as members. They are included on this list without regard to their political affiliation.
- Ahamd Abu Ilkhar Shukri
- Ahmad Muaz Al Khatib
- Riad Seif
- Ziad Abu Hamdan
- Suheir Al Atassi
- Abdul Karim Bakar
- Ali Sadr Il Din Al Bayanouni
- Ilya Mansour
- Mohamad Kamal Al Labwani
- Monzer Makhous
- Najib Al Ghadban
- Nagham Al Ghadri
- Noura Al Amir
- Walid Al Buni
- Yasser Salim
- Yahya Al Kurdi
- Burhan Ghalioun
- Haitham Al Maleh